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Lithium difluoro(oxalato)borate 409071-16-5 LiBF₂(C₂O₄)

Battery Grade

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Packag: Requirements of customers
Price:Negotiable

Product Description:

Lithium difluoro(oxalato)borate (LIODFB) [CAS 409071-16-5], is a novel boron-based lithium salt demonstrating exceptional performance in high-energy battery systems. This fluorinated oxalate-borate complex enables lithium-ion batteries with enhanced thermal stability (up to 180°C) and improved SEI formation characteristics, particularly in nickel-rich NCA/NMC cathodes. Ecovia's battery-grade LIODFB (purity >99.98%) exhibits ionic conductivity exceeding 8 mS/cm at 25°C while effectively suppressing aluminum current collector corrosion at voltages above 4.3V. As China's dominant LIODFB supplier, Ecovia supports next-generation battery architectures requiring extended cycle life (>2000 cycles at 1C rate) and improved safety parameters for premium EV applications, complying with stringent GB/T 33822-2017 standards for lithium battery additives.


Basic information
Product NameLithium difluoro(oxalato)borate
SynonymsLIF2OB;LIFOB;LIODFB;Lithium difluoro(ethanedioato)borate;Lithium oxalatodigluoroborate
CAS409071-16-5
Molecular FormulaLiBF₂(C₂O₄)
Molecular Weight143.76
EINECS803-919-2

 

Chemical Properties
Melting point265-271°C
Boiling point275.3℃ at 102kPa
Density2.01-2.065g/cm3 at 20℃
Storage tempInert atmosphere,Room Temperature
SolubilityWater (Slightly)
FormPowder
ColorWhite to Off-White

 

Safety Information
Hazard CodesXi
Risk Statements36/37/38
Safety Statements26
WGK Germany3

  Application  

Lithium difluoro(oxalato)borate (LIODFB) is a high performance lithium-ion battery salt with high cycle life, power capability, and low-temperature, high rate performance. It combines the advantages of lithium bis(oxalate)borate (LiBOB) and LiBF 4. LIODFB also stabilizes the solid electrolyte interface (SEI) on the surface of the graphite anode, and can be used as an additive to improve the cycling efficiency and capacity retention of the battery.

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